A cloud that looked white at lunchtime can appear peach, orange or pink near sunset. The cloud has not necessarily acquired a new ingredient. The light illuminating it has changed on its journey through the atmosphere, and the position from which you see it has changed as well.
The color belongs to a relationship among the Sun, the air, the cloud and the observer. That relationship is why the same patch of sky can change over a few minutes, even while the cloud itself seems almost still.
Sunlight contains a range of colors
What we perceive as white sunlight includes light across the visible spectrum. As light travels through air, molecules scatter some wavelengths more strongly than others. Shorter visible wavelengths are scattered more readily, contributing to the blue appearance of the daytime sky.
The National Weather Service explains that the sky's appearance also depends on the light available from the Sun and the sensitivity of human vision. It is not enough to say “the shortest color wins.” What reaches the eye and how the eye responds both belong in the explanation.
During the middle of a clear day, sunlight reaches the ground through a relatively shorter atmospheric path than it does near the horizon. The word relatively matters: the atmosphere is not a uniform pane of colored glass, and conditions along the path can vary greatly from one day to another.
Near the horizon, the journey is longer
When the Sun is low, its light travels through more atmosphere before reaching you or the clouds above you. More of the shorter-wavelength light can be scattered out of the direct path. The light that continues along that path can therefore be richer in warm colors.
A cloud can catch this warm illumination while the ground below it is already in shadow. That is one reason the evening sky can remain interesting after nearby buildings have become dim. Different cloud layers can catch different light, producing a bright high layer above a darker low layer.
The same geometry also explains why a cloud need not have a single color from edge to edge. One portion may face the remaining sunlight directly; another may be in shadow or illuminated indirectly. Texture and depth make the cloud a complicated surface rather than a flat projection screen.
Every evening supplies different materials
Cloud position, cloud thickness and particles in the air influence what you see. A completely overcast horizon can hide the part of the scene that would otherwise be vivid. A clear gap can let low sunlight reach clouds farther away. A spectacular sunset is therefore not guaranteed by the calendar or the temperature alone.
Avoid treating color as a dependable air-quality test. Particles can affect light, but the hue of a sunset does not tell you a pollutant concentration or whether the air is safe to breathe. For that question, use current measurements and the relevant local air-quality information.
Similarly, a photograph may not reproduce your experience exactly. A camera's exposure and white-balance choices can brighten or shift colors. A vivid image is not automatically false, but it is the product of a recording process as well as an atmospheric event. Two phones can present the same evening differently.
Look at the clouds around the Sun, safely
You can observe these changes without looking directly at the Sun. Choose a safe viewpoint and watch cloud color, shadows and the horizon away from its bright disk. Sunglasses, a camera screen or an ordinary phone lens should not be treated as equipment for direct solar observation.
Try noting which cloud layer brightens first, whether the underside differs from the edge, and how the colors change after a few minutes. A short sequence of ordinary sky photographs can help you compare the pattern later, provided taking them does not distract you near roads or other hazards.
The most rewarding detail may be how quickly a familiar scene becomes unfamiliar. A gray cloud can briefly glow and then return to gray as the geometry changes. Sunset makes the route taken by light visible, turning the atmosphere from an apparently empty space into an active part of the view.
Sources
- National Weather Service: Why is the sky blue?
Scattering and the longer atmospheric light path explain sky and sunset colors.